

act = actual temperature +/- ~15 C (estimated as described in J.Chem. Phys. 158, 114201 (2023))

Samples prepared and 2D-IR data acquired as described in "Distinctive signatures and ultrafast dynamics of Bronsted sites, silanol nests and adsorbed water in zeolites revealed by 2D-IR spectroscopy", 
Donaldson et al, Chemical Science 2025

2D-IR spectra are tab separated

The spectra at both temperatures are sign-inverted (i.e., against the convention of the above manuscript, the bleach is positive, ESA is negative). 
On plotting, the data can simply be multiplied by -1  
The sign of the 2D-IR spectra depends on the order of the phase cycling sequence used or equivalently the processing sequence, and was occasionally 
different on a particular run like this one. 

The pump axis is row 1
The probe axis of parallel and perpendicular detectors respectively are column 1

!!!!NOTE IN THE 240C D-ZSM-5 measurement, both detectors are measuring perpendicular probe polarisation.
This measurement was conducted in 2019, when parallel measurements had not yet been investigated